This indicator tracks major ions and nutrient levels in the waters of the Yellowknife, Cameron and Marian Rivers in the Northwest Territories (NWT). Major ions refer to certain elements dissolved in the water that appear commonly in many rivers worldwide. These elements can come from the surrounding landscape and the material the rivers flow upon. The major ions measured in this indicator are naturally occurring and include calcium (Ca2+), magnesium (Mg2+), sodium (Na+), potassium (K+), chloride (Cl-), silicon (Si) and sulphate (SO42-). Alkalinity, the ability to neutralize an acide, and silicon are also measured. Nutrients refer to dissolved molecules that play an important role for biological processes, and can help sustain life within waters.
The three rivers included in this indicator differ in underlying geology, ecology and surface area of their catchments but all are situated in an area containing discontinuous permafrost. The Yellowknife (19,353 km2) and Cameron River catchments drain the Taiga Shield. The Marian River drains an area of 23,608 km2 and straddles the Taiga Plains and Taiga Shield. Precambrian granites characterize much of the Taiga Shield, whereas the Taiga Plains are characterized by a lower density of lakes, abundance of peatlands and glacial deposits, such as tills)1,14. These rivers have been sampled monthly over a 30-year period and provide an excellent long-term dataset to evaluate changes to water chemistry over time in medium-sized nothern rivers. Data collected from these rivers was statistically analysed to determine significant monotonic trends with time. This dataset can provide a look at the current and historical geochemical trends for rivers draining the northern basins of Great Slave Lake.
Authors of this indicator are Pieter Aukes and Sherry Schiff, Unversity of Waterloo, Mike Palmer and Robin Staples, Government of the Northwest Territories (GNWT), and Michael English, Wilfrid Laurier University. Data are from Water Resources Division, Environment and Natural Resources, GNWT.
The NWT represents an area of Canada highly sensitive to a warming climate. Monitoring river water chemistry provides an indication to how NWT catchments are responding2. Specifically, changes to the dissolved constituents within a river can influence both aquatic health and drinking water quality. Surface waters act as a source of drinking water for many northern communities in the NWT. Furthermore, with increased industrial development and the continual need for sustainable drinking water resources, understanding baseline conditions allows for the determination of the current status of water quality in the NWT as well as potential future impacts from industry and a changing environment.
Long-term water quality monitoring information is critical for assessing the current and continued status of freshwater ecosystems. Northern environments are particularly sensitive to a warming climate3, but changes may occur on the decadal scale or longer. Therefore, long-term data from northern rivers are required to understand the influences of inter-annual and seasonal fluctuation in water quality4. Changes to water chemistry over time can be used as an indicator for environmental changes, either natural or anthropogenic, with watersheds2,5. Monitoring water chemistry over time can help create a better understanding of how aquatic systems respond to changes occuring on the landscape.
Current View: Status and Trends
Major ions in Yellowknife and Cameron Rivers (Taiga Shield catchments), and in the Marian River (part Taiga Plains and Taiga Shield catchment), NWT. Note the scale difference between the Marian and the other rivers.
Overall, concentrations of most major ions in the Marian River are much higher than either the Yellowknife or Cameron River. The Marian River catchment (containing peatlands and till) may be easier to erode and creates higher concentrations than the more resistant Precambrian bedrock found in the Taiga Shield. Marian River exhibits the greatest annual range in parameters (resulting from seasonal effects like river discharge) than the Yellowknife or Cameron Rivers. Concentrations of major ions in the Yellowknife and Cameron Rivers have increased significantly since 1995, with statistically significant increases found in calcium (Ca2+), magnesiu, (Mg2+), sodium (Na+), potassium (K+), chloride (Cl-), sulphate (SO42-) and alkalinity (ability to neutralize an acid). These results indicate that these Shield Rivers have been increasing in major ions for at least 15 years.
Nutrients in Yellowknife and Cameron Rivers (Taiga Shield catchments), and in the Marian River (part Taiga Plains and Taiga Shield catchment), NWT.
Concentrations of dissolved organic carbon (DOC) are relatively similar among all three rivers, where the Yellowknife and Marian Rivers contain significant increases over time. Annual concentration fluctuations can be observed, likely influenced by differences in seasonality and water discharge. Inorganic nitrogen concentrations are quite low for all three rivers. Marian River shows the only statistically significant increase in inorganic nitrogen (nitrate (NO3+) and nitrite (NO2-)) around 2007. Highest concentrations of inorganic nitrogen within the rivers have occurred within the last five years.
Geochemical changes have been observed in rivers across the Arctic and sub-Arctic, yet numerous factors are responsible for such changes (such as flow pathways or water residence time). Degradation of permafrost has been found to impact water quality through changes in organic matter6,7,8, increased nutrients such as increased nitrogen remineralisation9 and build-up of inorganic nitrogen in lakes10 or changes in major ions11. Although DOC increased in some rivers, major ion data from the NWT suggests similar trends to rivers found in other northern environments6,12, depicting changes to the current geochemical regime. It is possible that permafrost degradation contributes to the observed change in river chemistry, yet seasonality, changes to precipitation and contributing sources likely all contribute to a complex interaction of factors that impact water quality.
Under continued changing conditions, changes to sources and contributing areas within catchments are expected. For instance, a study of Arctic systems6 suggests a potential transition from surface water dominated systems to more groundwater dominated systems. Continued changes to seasonal soil thaws are believed to increase inorganic nitrogen exports into streams13, illustrating the potential for continued nutrient increases. The future also includes changing precipitation regimes, which will also affect river chemistry. A long-term study on the Baker Creek in the Taiga Shield10 observed a shift in stream flow regime within watershed from spring to fall months to occur around 1997, which is during the same period as the increase in major ions within all three rivers reported in this indicator.
Environmental watershed changes in the NWT include a number of complex interactions between terrestrial and aquatic environments, with a wide range of outcomes. However, long-term monitoring of these rivers allows for determination to how sub-Arctic rivers in the NWT are responding to such changes.
Found an error or have a question? Contact the team at NWTSOER@gov.nt.ca.
Ref. 1 - Ecosystem Classification Group. 2008. Ecological Regions of the Northwest Territoeis - Taiga Shield. Environment and Natural Resources. Yellowknife, NT. 146pp.
Ref. 2 - Holmes, R.M., B.J. Peterson, V.V. Gordeev, A.V. Zhulidov, M. Meybeck, R.B. Lammers and C.J. Vörösmarty. 2000. Flux of nutrients from Russia Rivers to the Arctic Ocean: can we estbalish a baseline against which to judge future changes? Water Resources Research 36(8): 2309-2320.
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Ref. 5 - Ouyang, Y., P. Nkedi-Kiza, Q.T. Wu, D. Shinde, C.H. Huang. 2006. Assessment of seasonal variations in surface water quality. Water Research 40:3800-3810.
Ref. 6 - Frey, K.E. and J.W. McClelland. 2009. Impacts of permafrost degradation on Arctic River biochemistry. Hydrological Processes 23: 169-182.
Ref. 7 - Olefeldt, D., M.R. Turetsky, and A. Persson. 2014. Influence of the permafrost boundary on dissolved organic matter characteristics in rivers with the Boreal and Taiga Plains of western Canada. Environmental Research Letters 9: 035005.
Ref. 8 - Coleman, K.A., M.J. Palmer, J.B. Korosi, S.V. Kokelj, K. Jackson, K. Hargan, C.J.C. Mushaphi, J.R. Thienpont, L.E. Kimpe, J.M. Blais, M.F.J. Pisaric, and J.P. Smol. 2015. Tracking the impacts of recent warming and thawing of permafrost peatlands on aquatic ecosystems: a multi-proxy approach using remote sensing and lake sediments. Boreal Environmental Research 20: 363-377.
Ref. 9 - Uhlířová, E., H. Šantrůčková, and S.P. Davidov. 2007. Quality and potential biodegradability of soil organic matter preserved in permafrost of Siberian tussock tundra. Soil Biology and Biochemistry 39: 1978-1989.
Ref. 10 - Spence, C., S.V. Kokelj, S.A. Kokelj, M. McCluskie, and N. Hedstrom. 2014. Evidence of a change in water chemistry in Canada's subarctic associated with enhanced winter streamflow. Journal of Geophysical Research: Biogeosciences 120: 113-127.
Ref. 11 - Frey, K.E., D.I Siegel, and L.C. Smith. 2007. Geochemistry of west Siberian streams and their potential response to permafrost degradation. Water Resources Research 43: W03406.
Ref. 12. - Frey, K.E., and L.C. Smith. 2005. Amplified carbon release from vast West Siberian peatlands by 2100. Geophysical Research Letters 32: L09401.
Ref. 13 - Harms, T.L. and J.B. Jones Jr. 2012. Thaw depth determines reaction and transport of inorganic nitrogen in valley bottom permafrost soils. Global Change Biology 18: 2958-2968.
Ref. 14 - Ecosystem Classification Group. 2007 (rev. 2009). Ecological regions of the Northwest Territories - Taiga Plains. Environment and Natural Resources. Yellowknife, NT. 173pp.